Trimethyl2trimethylsilylmethylbenzylammonium iodide. View enhanced pdf access article on wiley online library html view download pdf for offline viewing. Articles of trimethylsilyl iodide are included as well. Trimethylsilyl trifluoromethanesulfonate cas 27607778. Find support for a specific problem on the support section of our website. Buy trimethyl2trimethylsilylmethylbenzylammonium iodide cas 83781479, a product for proteomics research, from santa cruz.
In the reaction of trimethylsilyl iodide with esters the silyl group acts as an activating lewis acid, while the iodine attacks as the nucleophile. Structure, properties, spectra, suppliers and links for. Trimethylsilyl iodide may be prepared by the oxidative cleavage of hexamethyldisilane by iodine or by the cleavage of hexamethyldisiloxane with aluminium. Buy trimethylsilyl trifluoromethanesulfonate cas 27607778, a strong silylating agent, from santa cruz. Efficiency conversion of trimethylsilyl ethers to their corresponding ethers using carbon.
Based solid acid as a new catalyst in heterogeneous mixtures. Observation by flow 1h nmr and dimerization kinetics and. Chemical properties of iodotrimethylsilane cas 16029984 download as pdf file download as excel file download as 2d mole file predict properties. The use of organosilicon compounds in synthesis is described. Trimethylsilyl iodide 16029984 pricing, chemical properties, structure, cas number, molecular formula. Thus, in the presence of 1, the following conversions are reported to occur efficiently and under mild conditions. Abstract the ability of trimethylsilyl iodide 1 to effect a variety of useful synthetic transformations has been amply demonstrated. In particular the use of trimethylsilyl iodide, silyloxydienes, and vinyl iodides are highlighted, several structural organosilicon studies are. Diethyl 2lithiothiophene5phosphate 3 was prepared from diethyl thiophene2phosphate 4 by. I would like to demethylate a substrate which carries one aryl methoxy group and heterocycle moieties. Media in category trimethylsilyl iodide the following 4 files are in this category, out of 4 total. Trimethylsilyl iodide an overview sciencedirect topics. It is a colorless, volatile liquid at room temperature. Trimethylsilyl iodide iodotrimethylsilane or tmsi is an organosilicon compound with the chemical formula ch 3 3 sii.
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